Fire Emissions and Smoke Dispersion
How much pollution does a wildfire release, and where will the smoke go? Fire emissions depend on fuel consumption and combustion efficiency, while smoke dispersion follows atmospheric transport. This model derives emission factor equations, implements plume rise models, demonstrates Gaussian dispersion, and maps air quality impacts from wildfire smoke.
Prerequisites: emission factors, plume rise, gaussian dispersion, particulate transport
1. The Question
What is the air quality impact 50 km downwind from this wildfire?
Fire emissions:
Pollutants released during combustion.
Major species:
- CO₂ (carbon dioxide): ~1650 g/kg fuel
- CO (carbon monoxide): ~60-100 g/kg
- PM₂.₅ (fine particles): ~10-20 g/kg
- NOₓ (nitrogen oxides): ~1-3 g/kg
- VOCs (volatile organics): ~10-30 g/kg
- CH₄ (methane): ~5-10 g/kg
Health impacts:
PM₂.₅ primary concern:
- Respiratory issues
- Cardiovascular stress
- Premature mortality
Air quality standards:
EPA: 35 μg/m³ (24-hour PM₂.₅)
Wildfire smoke: 100-500 μg/m³ common, >1000 μg/m³ near fires
Applications:
- Air quality forecasting
- Evacuation decisions
- Health advisories
- Climate forcing calculations
- Carbon accounting
2. The Conceptual Model
Emission Factors
Mass of pollutant per mass of fuel:
\[EF_i = \frac{m_i}{m_{\text{fuel}}}\]Where:
- $EF_i$ = emission factor for species $i$ (g/kg)
- $m_i$ = mass of species emitted
- $m_{\text{fuel}}$ = dry fuel consumed
Total emissions:
\[E_i = A \times B \times C \times EF_i\]Where:
- $A$ = area burned (ha)
- $B$ = fuel loading (kg/ha)
- $C$ = combustion completeness (fraction, 0-1)
Modified combustion efficiency (MCE):
\[MCE = \frac{\Delta CO_2}{\Delta CO_2 + \Delta CO}\]Flaming: MCE > 0.95 (high efficiency, less PM)
Smoldering: MCE < 0.85 (low efficiency, more PM, CO)
PM₂.₅ increases as MCE decreases:
\[EF_{PM_{2.5}} = a - b \times MCE\]Typical: $a = 60$, $b = 50$ → flaming = 12.5 g/kg, smoldering = 17.5 g/kg
Plume Rise
Buoyancy-driven ascent:
Hot emissions rise above fire.
Final plume height:
\[H = H_s + \frac{1.6 F^{1/3}}{U s^{1/3}}\]Where:
- $H$ = plume top height (m)
- $H_s$ = stack (fire) height (m)
- $F$ = buoyancy flux (m⁴/s³)
- $U$ = wind speed (m/s)
- $s$ = stability parameter
Buoyancy flux:
\[F = g \frac{Q_H}{c_p T_a \rho_a}\]Where:
- $g$ = 9.81 m/s²
- $Q_H$ = sensible heat flux (W)
- $c_p$ = 1005 J/kg/K
- $T_a$ = ambient temperature (K)
- $\rho_a$ = air density (kg/m³)
Typical wildfire:
$Q_H = 10^8$ W → plume rise 1000-3000 m
Gaussian Dispersion
Concentration downwind:
\[C(x,y,z) = \frac{Q}{2\pi U \sigma_y \sigma_z} \exp\left(-\frac{y^2}{2\sigma_y^2}\right) \left[\exp\left(-\frac{(z-H)^2}{2\sigma_z^2}\right) + \exp\left(-\frac{(z+H)^2}{2\sigma_z^2}\right)\right]\]Where:
- $C$ = concentration (μg/m³)
- $Q$ = emission rate (μg/s)
- $U$ = wind speed (m/s)
- $\sigma_y, \sigma_z$ = dispersion parameters (m)
- $H$ = effective release height (m)
- Second exponential = ground reflection
Dispersion parameters:
Power-law with distance:
\(\sigma_y = a x^b\) \(\sigma_z = c x^d\)
Constants depend on atmospheric stability class.
Ground-level concentration (z=0):
\[C(x,y,0) = \frac{Q}{\pi U \sigma_y \sigma_z} \exp\left(-\frac{y^2}{2\sigma_y^2}\right) \exp\left(-\frac{H^2}{2\sigma_z^2}\right)\]3. Building the Mathematical Model
Total Emissions Calculation
Fuel consumption:
\[FC = A \times FL \times CC\]Where:
- $FC$ = fuel consumed (kg)
- $A$ = burned area (m²)
- $FL$ = fuel loading (kg/m²)
- $CC$ = combustion completeness
Species emission:
\(E_i = FC \times EF_i \times 10^{-6}\) (tonnes)
Example:
Area = 1000 ha = 10⁷ m²
Fuel loading = 1.5 kg/m² (forest)
CC = 0.9
$EF_{PM_{2.5}}$ = 15 g/kg
Over 200 tonnes of PM₂.₅!
Emission Rate
Temporal distribution:
Fire burns over time $T$ (hours/days).
Emission rate:
\[Q(t) = \frac{E_i}{T} \times f(t)\]Where $f(t)$ = temporal distribution (peak during active burning).
Simplified: Assume constant during active burning period.
\(Q = \frac{E_i}{T \times 3600}\) (g/s)
Stability Class
Pasquill-Gifford classes:
A: Extremely unstable (strong solar heating, light winds)
B: Moderately unstable
C: Slightly unstable
D: Neutral
E: Slightly stable
F: Moderately stable (clear night, light winds)
Affects dispersion:
Unstable (A-C): Rapid vertical mixing, lower ground concentrations
Stable (E-F): Limited mixing, concentrated plume
Wildfire context:
Heat from fire creates instability → often class C-D even at night.
4. Worked Example by Hand
Problem: Calculate PM₂.₅ emissions and downwind concentration.
Fire characteristics:
- Burned area: 500 ha
- Fuel type: Conifer forest
- Fuel loading: 2.0 kg/m²
- Combustion completeness: 85%
- Burn duration: 8 hours
Meteorology:
- Wind speed: 5 m/s
- Stability: Class C (slightly unstable)
- Plume height: 800 m
Location of interest:
- Downwind distance: 20 km
- Lateral offset: 2 km
Calculate total PM₂.₅ and ground-level concentration.
Solution
Step 1: Fuel consumed
\[A = 500 \times 10^4 = 5 \times 10^6 \text{ m}^2\] \[FC = 5 \times 10^6 \times 2.0 \times 0.85 = 8.5 \times 10^6 \text{ kg}\]Step 2: PM₂.₅ emission
$EF_{PM_{2.5}} = 15$ g/kg (typical conifer)
\[E_{PM_{2.5}} = 8.5 \times 10^6 \times 15 = 1.275 \times 10^8 \text{ g} = 127.5 \text{ tonnes}\]Step 3: Emission rate
\[Q = \frac{1.275 \times 10^8}{8 \times 3600} = \frac{1.275 \times 10^8}{28800} = 4427 \text{ g/s}\]Step 4: Dispersion parameters (Class C, x=20 km)
From standard tables:
\[\sigma_y = 0.20 \times 20000^{0.894} = 0.20 \times 8913 = 1783 \text{ m}\] \[\sigma_z = 0.14 \times 20000^{0.885} = 0.14 \times 8318 = 1164 \text{ m}\]Step 5: Concentration at (x=20 km, y=2 km, z=0)
\[C = \frac{4427}{\pi \times 5 \times 1783 \times 1164} \exp\left(-\frac{2000^2}{2 \times 1783^2}\right) \exp\left(-\frac{800^2}{2 \times 1164^2}\right)\] \[= \frac{4427}{32.5 \times 10^6} \times \exp(-0.63) \times \exp(-0.24)\] \[= 1.36 \times 10^{-4} \times 0.533 \times 0.787\] \[= 5.7 \times 10^{-5} \text{ g/m}^3 = 57 \text{ μg/m}^3\]Step 6: Interpret
57 μg/m³ exceeds EPA standard (35 μg/m³)
Health advisory warranted at this location.
Directly downwind (y=0): Concentration would be ~107 μg/m³ (worse)
5. Computational Implementation
Below is an interactive smoke dispersion simulator.
Total PM₂.₅: -- tonnes
Max concentration: -- μg/m³
Distance to standard: -- km
Observations:
- Concentration decreases with distance as plume disperses
- Higher plume rise reduces ground-level concentrations
- Unstable atmosphere promotes mixing (lower peak concentrations)
- EPA standard often exceeded 10-30 km downwind
- Larger fires produce proportionally more emissions
- Wind speed dilutes concentrations but transports farther
Key insights:
- Smoke impacts extend far beyond fire perimeter
- Atmospheric stability critically affects dispersion
- PM₂.₅ health risks significant at large distances
- Multiple factors determine air quality impacts
6. Interpretation
Health Impacts
PM₂.₅ exposure effects:
Short-term (hours-days):
- Respiratory irritation
- Asthma attacks
- Reduced lung function
Long-term (weeks-months):
- Cardiovascular events
- Premature mortality
- Chronic conditions
Vulnerable populations:
- Children
- Elderly
- Respiratory disease
- Cardiovascular disease
2020 California fires:
Estimated 1200-3000 premature deaths from smoke exposure.
Economic impact: $10-80 billion (health costs).
Air Quality Forecasting
BlueSky framework:
- Fuel consumption: From fire progression models
- Emissions: Apply emission factors
- Dispersion: HYSPLIT or CALPUFF models
- Forecast: 1-3 day PM₂.₅ predictions
Operational use:
NOAA Smoke Forecasting System (daily products).
Applications:
- Public health advisories
- School closures
- Outdoor event cancellations
- Hospital preparedness
Carbon Accounting
CO₂ emissions:
\[E_{CO_2} = FC \times 1650 \text{ g/kg}\]Example: 10 million hectares burned globally (annual average)
Fuel loading ~1.5 kg/m², CC = 0.9:
\[FC = 10^{10} \times 1.5 \times 0.9 = 1.35 \times 10^{10} \text{ kg}\] \[E_{CO_2} = 1.35 \times 10^{10} \times 1650 \times 10^{-12} = 22.3 \text{ Gt CO}_2\]~5% of global fossil fuel emissions!
7. What Could Go Wrong?
Injection Height Uncertain
Plume rise depends on fire intensity, atmospheric stability.
Under-prediction:
Plume rises higher than modelled → lower ground concentrations (false alarm).
Over-prediction:
Plume doesn’t rise → higher ground concentrations (missed hazard).
Example - 2003 Canberra:
Pyrocumulonimbus (fire-generated thunderstorm) injected smoke to 15 km (vs predicted 3 km).
Solution: Real-time satellite observations (GOES, MODIS).
Complex Terrain
Gaussian model assumes flat terrain, uniform meteorology.
Mountains:
- Channeled flows (valleys)
- Slope winds
- Thermal circulations
Result: Smoke pooling in valleys, unpredicted transport.
Solution: CALPUFF (puff model) or WRF-Chem (3D meteorology + chemistry).
Chemistry Ignored
Simple models: Transport PM₂.₅ as inert tracer.
Reality:
Photochemical aging:
- VOCs + NOₓ → ozone, secondary PM
- PM₂.₅ mass increases downwind
- Composition changes
Solution: Chemical transport models (CMAQ, WRF-Chem).
Background PM Not Considered
Model predicts fire contribution only.
Total exposure:
\[PM_{total} = PM_{background} + PM_{fire}\]Urban areas:
$PM_{background}$ = 10-20 μg/m³ (normal)
Fire adds 30 μg/m³ → total = 40-50 μg/m³
Exceeds standard even though fire alone wouldn’t.
8. Extension: Satellite-Based Emissions
Bottom-up (models):
Fire area × fuel × EF (this model’s approach).
Top-down (satellites):
Directly observe emissions from space.
Fire radiative power (FRP):
Thermal emission from fire (MW).
FRP to emissions:
\[E_i = FRP \times CE_i\]Where $CE_i$ = conversion efficiency (g/MJ).
Advantages:
- Near real-time
- No fuel data needed
- Global coverage
Sensors:
- MODIS: 1 km, 4× daily
- VIIRS: 375 m, 2× daily
- GOES: 2 km, 5-15 min
Example - GFAS (Global Fire Assimilation System):
Copernicus service, daily global fire emissions.
9. Math Refresher: Gaussian Function
Standard Form
\[f(x) = \frac{1}{\sigma\sqrt{2\pi}} \exp\left(-\frac{(x-\mu)^2}{2\sigma^2}\right)\]Where:
- $\mu$ = mean
- $\sigma$ = standard deviation
Properties:
- Symmetric around $\mu$
- Total area = 1 (probability distribution)
- 68% within ±σ, 95% within ±2σ
Two-Dimensional
\[f(x,y) = \frac{1}{2\pi\sigma_x\sigma_y} \exp\left(-\frac{x^2}{2\sigma_x^2} - \frac{y^2}{2\sigma_y^2}\right)\]Dispersion plume:
Concentration follows Gaussian in crosswind (y) and vertical (z).
Peak concentration: On centerline (y=0, z=H).
Summary
- Fire emissions quantified using emission factors relating pollutant mass to fuel consumed
- PM₂.₅ primary health concern with emission factors 10-20 g/kg fuel varying by fire type
- Plume rise driven by buoyancy determines effective release height for dispersion
- Gaussian dispersion model predicts ground-level concentrations based on meteorology
- Atmospheric stability critically affects smoke dispersion and ground concentrations
- Applications span air quality forecasting, health advisories, carbon accounting
- 2020 California fires estimated 1200-3000 premature deaths from smoke exposure
- Challenges include injection height uncertainty, complex terrain, atmospheric chemistry
- Satellite observations provide real-time emissions estimates via fire radiative power
- Critical tool for public health protection during wildfire events